Saccharide mercaptals

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

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536 175, 536 54, 536124, C07H 100, C08B 3700

Patent

active

053150023

ABSTRACT:
Process for the preparation of a mercaptal of an oligosaccharide which process comprises the step of reacting the oligosaccharide with a thiol in the presence of an aqueous halocarboxylic or halosulphonic acid.

REFERENCES:
patent: 3635717 (1972-01-01), Ohi
Jager et al, The stepwise degradation of a glycosylated aldose. A potential method for sequencing branched oligosaccharides, Carbohydrate Research, vol. 217, 18 Sep. 1991, pp. 99-106.
Gorin, The configuration of Glycosidic Linkages in Oligosaccharides, Canadian Journal of Chemistry, vol. 40, 1962, pp. 275-282.
Englmaier, High Resolution-GLC of Carbohydrates as their Dithioacetal-Trimethylsilylates and Trifluoroacetates, Journal of High Resolution Chromatography, vol. 13, No. 2, 1990, pp. 121-125.

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