Ruthenium complexes, process for preparation thereof, and...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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Details

C526S283000, C525S332100, C525S338000, C585S277000, C546S004000, C556S136000

Reexamination Certificate

active

07084222

ABSTRACT:
The present invention relates to ruthenium complex compound wherein a heteroatom-containing carbene compound having a six-membered ring structure is bonded to ruthenium and a process for the preparation thereof; a process for producing ring-opened cyclic olefin polymer by subjecting a cyclic olefin to ring-opening metathesis polymerization in the presence of such a ruthenium complex compound; and a process for producing hydrogenated product of ring-opened cyclic olefin polymers by hydrogenating the carbon-carbon double bonds of the above ring-opened polymers. The invention gives hydrogenated product of ring-opened cyclic olefin polymers having physical properties different from those of hydrogenated product of ring-opened polymers of the prior art. Particularly, the use of dicyclopentadiene can give a hydrogenated product of ring-opened cyclic olefin polymer excellent in heat resistance, and this product can be advantageously used as parts or formed products for medical appliances or electrical components.

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Junji Kodemura et al.; Polymer Journal, vol. 27, No. 12, pp. 1167-1172, 1995.
Richard R. Schrock; Metathesis Polymerization of olefins and Polymerization of Olefins and Polymerization of Alkynes, 1996, p. 1, Kluwer Academic Publisher, Boston.

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