Reversible oxygen sorbent compositions

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

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546 2, 556118, 556138, 556140, C07F 1506

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active

052083357

ABSTRACT:
High Capacity solid state cyanocobaltate complexes represented by the chemical formula:

REFERENCES:
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patent: 4251452 (1981-02-01), McAuliffe
patent: 4477418 (1984-10-01), Mullhaupt et al.
patent: 4830999 (1989-05-01), Drago et al.
R. S. Drago et al., "Entrapment of an Anionic Stable Moisture-Resistant Oxygen Carrier in Zeolite Y", J. Amer. Chem. Soc., 110, p. 304, (1988).
G. A. Kozlov et al., "Structure and Properties of the Products of Reaction Between Molecular Oxygen and New Salts of Pentacyapnocobaltate (II) Anion," Translated from Teoreticheskayadiaks Eperimental'naya Khimiya, 17, (5) 686 1983.
S. Imamura, et al., "Separation of Oxygen from Air by [Co.sub.II (bpy)(terpy)].sup.2+ Complexes in Zeolite Y", Langmuir 1985, 1, 326-(1985).
R. J. Taylor et al., "Characterization of a Cobalt (II) Cyanide Complex Inside Zeolite Y that Reversibly Binds Oxygen", J. Amer. Chem. Soc., 111, 6610, (1989).
S. J. Carter, et al., "Cobalt (II) Cyanides in Aprotic Media: Effect of Varying Counterino and Solvent", Inorg. Chem., (1986), 25, 2888-2894.
S. J. Carter, "Synthesis, Characterization and Reactions of New Organocyanocobaltates", Thesis Brandeis University, 1988.
J. H. Hildebrand, "The Thermal Dissociation of Barium Peroxide", J. Amer. Chem. Soc., 34, p. 246, (1912).

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