Resist materials

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

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430 5, 430313, 430326, 558 44, 558 58, G03F 7004

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active

058306196

ABSTRACT:
Photoacid generators advantageous for use in applications such as photoacid generators used in chemically amplified resists are disclosed. These compounds are based on an ortho nitro benzyl configuration employing an .alpha. substituent having high bulk, steric characteristics, and electron withdrawing ability. The enhanced efficacy is particularly found in compounds both having a suitable .alpha. substituent and a second ortho substituent with large electron withdrawing and steric effects.

REFERENCES:
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patent: 5200544 (1993-04-01), Houlihan et al.
Loudon et al., J. Chem. Soc., 1959, 1780-2.
"Substituent Constants for Correlation Analysis in Chemistry and Biology", Hansch, C. et al., Steric Effects in Organic Chemistry, pp. 559-675 (1956).
"The Upsilon Steric Parameter", Steric Effects in Drug Design, pp. 58-91 (1983).
"Electrical Effect Substituent Contents for Correlation Analysis", Progress in Physical Organic Chemistry, vol. 13, pp. 119-247 (1981).
"N-alkanesulfonamide Dianions: Formation and Chemoselective C-Alkylationa", M. E. Thompson, J. Org. Chem., 49, pp. 1700-1703, (1984).
"Chemical Amplification Mechanisms for Microlithography", Reichmanis, E. et al., Chemisty of Materials (1991), 3, pp. 394.
"Chemical Amplification Mechanisms for Microlithography", by Reichmanis, E. et al.

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