Reactivation of a phosphorus-vanadium-oxygen complex oxidation c

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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Details

2603464, 26034675, 260524R, 260533R, 260533N, 260546, 260597R, 260604R, B01J 2392, B01J 2728, C07D30760, C07D30789

Patent

active

040898075

ABSTRACT:
The present disclosure relates to a method of reactivation of phosphorus-vanadium-oxygen complex catalysts which are useful in the oxidation of hydrocarbons in particular acylic aliphatics such as alkanes or alkenes to oxidation products including aldehydes, ketones, acids and anhydrides. The present method of reactivation is implemented by passing selected halide containing materials over the catalyst at reactivation conditions to effect formation of a volatile vanadium compound which is removed from the catalyst. This procedure is applicable to reactivation of catalyst which during normal oxidation process become deactivated.

REFERENCES:
patent: 4020174 (1977-04-01), Partenheimer

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