Radiation-sensitive compositions of polymers containing a .pi.-m

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

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430270, 430923, 430927, 20415914, G03C 171

Patent

active

045031401

ABSTRACT:
Radiation-sensitive polymeric compositions containing metal-carbonyl complexes and the cured insoluble crosslinked resin produced therefrom are disclosed. When coated as a layer on a substrate, the composition is useful as an element in the graphic arts.

REFERENCES:
patent: 4127506 (1978-11-01), Gray et al.
patent: 4252671 (1981-02-01), Smith
patent: 4252675 (1981-02-01), Smith
patent: 4252676 (1981-02-01), Smith
patent: 4361497 (1982-11-01), Boldt et al.
Charles U. Pittman, Jr., et al., "Copolymerization of Styrenetricarbonylchromium and the Reaction of Polystyrene with Chromium, Molybdenum, and Tungsten Hexacarbonyl", American Chemical Society, Div. Org. Coatings Plast. Chem., vol. 31, No. 2, pp. 325-329, (1971).
Pittman, Charles U. Jr., "Vinyl Polymerization of Organic Monomers Containing Transition Metals", pp. 1-61, of vol. 6 of a monographic series titled Organometallic Reactions, edited by E. I. Becker and M. Tsutsui, Interscience Publishers, (1977).
Wagner, H. M. and Purbrick, M. D., "Transition Metal Carbonyl Derivatives as Photopolymerization Initiators and Photocrosslinking Agents in Photoresists", R.P.S. Conference, Cambridge, England, (1981).

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