Quadrupole ion trap device and methods of operating a...

Radiant energy – Ionic separation or analysis – Methods

Reexamination Certificate

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C250S292000, C250S290000

Reexamination Certificate

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10494493

ABSTRACT:
A quadrupole ion trap device has a field adjusting electrode located outside the trapping region adjacent the aperture in the entrance end cap electrode, and optionally adjacent the aperture in the exit end cap electrode. The field adjusting electrode(s) controls field distortion in the vicinity of the apertures. By appropriately setting the voltages on the field adjusting electrodes the efficiency and resolution of operational processes such as ion introduction, precursor ion isolation and mass scanning can be improved.

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J. Mitchell Wells, Wolfgang R. Plass, R. Graham Cooks, Control of Chemical Mass Shifts in the Quadrupole Ion Trap Through Selection of Resonance Ejection Working Point and rf Scan Direction, Analytical Chemistry, vol. 72, No. 13, Jul. 1, 2000, pp. 2677-2683.

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