Production method of diffraction grating

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Making named article

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430945, G02B 518, G02B 112

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057167621

ABSTRACT:
This invention provides a method of producing a diffraction grating of a spectroscope by applying light to a thin film of glass having characteristics such that a density change occurs with the change of a glass structure upon irradiation of light and volume expansion occurs irreversibly. The method comprises applying light to a diffraction grating formation of a surface of the thin film by applying light through a phase mask or applying interference light, and causing the light irradiation portion of glass to expand and to thereby form the diffraction grating. Light to be applied is generally laser beams of ultraviolet rays, such as an excimer laser, a Nd-YAG laser or UV higher harmonics of a dye laser. A laser beam of a visible light region can be used, too. Preferably, a silica single crystal plate is used for the substrate of the thin film, and sputter vacuum deposition is used for forming the thin film. The glass composition whose volume expands upon irradiation of light is GeO.sub.2 --SiO.sub.2 type glass having a GeO.sub.2 content of 20 to 95 mol %, but this composition is not particularly limitative, and any glass compositions can be used so long as they have a high volume expansion coefficient.

REFERENCES:
patent: 4877717 (1989-10-01), Suzuki et al.
patent: 5028105 (1991-07-01), Drexhage et al.
patent: 5287427 (1994-02-01), Atkins et al.

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