Processes for the preparation of...

Organic compounds -- part of the class 532-570 series – Organic compounds – Nitrogen attached directly or indirectly to the purine ring...

Reexamination Certificate

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C544S330000, C514S275000

Reexamination Certificate

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10523753

ABSTRACT:
Processes for the preparation of 4-[[4-[[4-(2-cyanoethenyl)-2,6-dimethylphenyl]-amino]-2-pyrimidinyl]amino]benzonitrile of formula (I), a N-oxide, a pharmaceutically acceptable acid addition salt, a quaternary amine or a stereochemically isomeric form thereof are provided, said processes comprise:a) reacting 4-(2-cyanoethenyl)-2,6-dimethylbenzenamine with an intermediate of formula (III) in the presence of a suitable solvent;b) reacting an intermediate of formula (IV) with acrylonitrile in the presence of a suitable palladium catalyst, a suitable base and a suitable solvent;c) dehydrating the corresponding amide of the compound of formula (I).

REFERENCES:
patent: WO 01/85700 (2001-11-01), None
patent: WO 03016306 (2003-02-01), None
International Search Report dated Nov. 6, 2003 for corresponding Appln. No. PCT/EP 03/50366.
International Preliminary Examination Report dated Nov. 30, 2004 for corresponding Appln. No. PCT/EP 03/50366.

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