Process of manufacture of flourinated alkyladamantanes

Details Process of manufacture of flourinated alkyladamantanes Process of manufacture of flourinated alkyladamantanes

1976-01-12

1977-08-09

Gantz, Delbert E.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07C 2318

Patent

active

040410862

ABSTRACT:
Novel, highly fluorinated hydrocarbons derived from the fluorination of alkyladamantanes, may be produced by known means, as for example by the process comprising contacting an alkyladamantane hydrocarbon, in vapor phase, with a fluoride of a transition metal (e.g., CoF.sub.3, MnF.sub.3, AgF.sub.2) at 200.degree.-400.degree. C. The preferred adamantane hydrocarbons contain in the range of 11-30 (more preferred 12 to 14) carbon atoms and contain methyl and/or ethyl groups.

REFERENCES:
patent: 3641167 (1972-02-01), Moore et al.
Chemical Abstracts, 85:142719v.
Chemical Abstracts, 85:934732.
Lovelace et al., Aliphatic Fluorine Compounds, pp. 10-12, (1958).
Stacey et al., Advances in Fluorine Chemistry, vol. 1, 166-175, 182-183, (1962).

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