Process of making linear alpha-olefins by ethylene oligomerizati

Details Process of making linear alpha-olefins by ethylene oligomerizati Process of making linear alpha-olefins by ethylene oligomerizati

1975-10-01

1976-09-21

Davis, C.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07C 320

Patent

active

039819418

ABSTRACT:
A process for making linear alpha-olefins by oligomerization of ethylene in the presence of a catalyst comprising titanium halide-organoaluminum halide (e.g., titanium tetrachloride-ethylaluminum dichloride) and a halogenated phosphorus compound (e.g., PCl.sub.3) provides oligomers of high alpha-purity and high selectivity to linear alpha-olefins with excellent control of product molecular weight.

REFERENCES:
patent: 3574782 (1971-04-01), Bearden et al.
patent: 3686350 (1972-08-01), Yamada et al.

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