Process of forming a refractory metal thin film

Coating processes – Direct application of electrical – magnetic – wave – or... – Plasma

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427534, 4272554, 427250, 427309, 427 99, 4273722, H05H 124, C23C 1608

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061433772

ABSTRACT:
A process for forming a refractory metal thin film on a substrate by subjecting a gaseous mixture containing a halide of a refractory metal and the hydrogen gas to a plasma chemical vapor deposition, comprising the step of adjusting a mixing ratio of the halide of the refractory metal to the hydrogen gas to a relatively small value at an initial stage of the process and, subsequent to the initial stage of the process, adjusting the mixing ratio of the halide of the refractory metal to the hydrogen gas to a relatively large value.

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A. Kishimoto, Jpn. J. Appl. Phys. 29(10) p. 2273, Oct. 1990.

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