Process for the production of high purity zirconium tetrafluorid

Chemistry of inorganic compounds – Halogen or compound thereof – Binary fluorine containing compound

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C01F 750, C01G 2504, C01G 2704

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049833731

ABSTRACT:
High purity metal fluorides (ZrF.sub.4, HfF.sub.4, AlF.sub.3) are produced by incomplete reaction of metal or their compounds with elemental fluorine and subsequent elevated temperature sublimation of the metal fluoride from the reaction products wherein unreacted metal or metal compounds act as "getters" to convert volatile impurity metal fluorides to non-volatile metals or metal compounds.

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patent: 4652438 (1987-03-01), Fulweiler
T. Tatsuno; "Synthesis of Iron-Impurity Free ZrF.sub.4 "; Material Science Forum, vols. 19-20 (1987) pp. 181-185.
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R. C. Fulweiler, Barry C. Farnsworth; "Advances in Chemical Vapor Purification"; 5th Int'l Symp. on Halide Glasses (Jun. 1988) pp. 533-538.
J. A. Sommers, V. Q. Perkins; "Research and Development for Commercial Production of High Purity ZrF.sub.4 and HfF.sub.4 ;" 1988, pp. 169-173.
K. Fujiura, Y. Ohishi, S. Sakaguchi, Y. Terunuma; "Synthesis of High Purity ZrF.sub.4 by Chemical Vapor Deposition"; 5th Int'l Symp. of Halide Glasses (1988) pp. 174-179.
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H. M. Haendler, S. F. Bartram, R. S. Becker, W. J. Bernard, S. W. Bukata; "The Reaction of Fluorine with Titanium, Zirconium and the Oxides of Titanium (IV); Zirconium (IV) and Vanadium (V)"; 11-10-53; pp. 2177-2178.
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