Process for the production of electroluminescence element, elect

Chemistry: electrical and wave energy – Processes and products – Coating – forming or etching by sputtering

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2041921, 20419215, 20419229, C23C 1434

Patent

active

058535527

ABSTRACT:
A process for producing an electroluminescence element provided with a luminescent layer sandwiched between two electrodes on an insulating substrate, the luminescent layer being composed of a host material with a luminescent center element added. The process comprises a step of forming the aforesaid luminescent layer as a film onto the insulating substrate by either sputtering or evaporation, by use of a source material composed of a compound of an element of Group II and an element of Group VI, to which a halide of a rare earth element is added as the luminescent center element. The atmosphere at the time of the film formation contains either a halogen gas or halide gas. The aforesaid luminescent layer is formed as a film onto the insulating substrate by either sputtering or evaporation, by use of a source material composed of the aforesaid compound of an element of Group II and an element of Group VI, to which a fluoride or fluorine compound of the luminescent center element and a halide other than fluoride of the element of Group II are added. The film formation atmosphere may be pretreated with a chlorine-containing gas prior to a film formation step of forming the luminescent layer as a film onto the insulating substrate by a sputtering method by use of a source material composed of the host material with the luminescent center element. An electro-luminescence element is further disclosed, wherein the X-ray diffraction spectrum thereof has only a single peak at an X-ray diffraction angle from the luminescent layer, ranging from 25.degree. to 30.degree. according to a thin film X-ray diffraction measuring method using Cu-Kd radiation, and no other peaks of the X-ray diffraction spectrum exist at an X-ray diffraction angle of approximately 27.degree..

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U.S. application No. 08/197,492, filed Feb. 1994.
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Ohwaki et al., High-Brightness Blue, Red, and Stable Green Thin-Film Electroluminescent Devices, Electrical Communications Laboratories, 1987, pp. 811-818.
Hirabayashi et al., Color Electroluminescent devices prepared by Metal Organic Chemical Vapor Deposition, Japanese Journal of Applied Physics, Sep. 1987, vol. 26; No. 9, pp. 1472-1476.
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