Process for the preparation of high purity calcium titanate hydr

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

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423637, 423608, 501136, 106449, C01G 2304, C01F 1102

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active

050826484

ABSTRACT:
A process for the preparation of high purity calcium titanate hydrates, particularly various forms of kassite, is disclosed. Calcium carbonate and titanium tetraisopropoxide are used as starting materials. The process utilizes a hydrothermal reaction step. Hydrates having both hexagonal plate form, wherein the particles have a hexagonally shaped flat plate-like morphology, and lath form, wherein the particles have a rod-like morphology are produceable according to the process. Particle morphology is determined by the choice of process parameters, especially the rate of heating during the hydrothermal reaction step. Kassite particles of the hexagonal plate form, which are useful as a high opacity paper coating pigment, are produced when the rate of heating is less than or equal to 1.5.degree. C./min. Faster rates of heating result in kassite particles of a lath form. These particles are useful as a reinforcing material in polymers and ceramics.

REFERENCES:
Mitsuhashi et al., "Brookite Formation from Precipitates Containing Calcium Ions", Mineralogical Jr., vol. 9, No. 4, 1978, pp. 236-240.
Evans et al., "Kassite from the Diamond Jo Quarry, Magnet Cave, Hot Spring County, Ark.: The Problem of Cafetite and Kassite", American Mineralogist, vol. 71, 1986, pp. 1045-1048.
Rudashevskii et al., "Synthetic Analog and Refinement of the Properties of Kassite and Hydrokassite", Mineral and Geo. Chem., vol. 106, No. 1, pp. 114-20, 1977.
Kisel et al., "Calcium Dititanate", Neorganicheskie Materialy, vol. 8, No. 10, pp. 1782-1785, Oct., 1972.

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