Process for the preparation of bicycloalkane derivatives

Details Process for the preparation of bicycloalkane derivatives Process for the preparation of bicycloalkane derivatives

1975-12-18

1977-10-04

Gerstl, Robert

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603405AS, 2603407, 2603409AS, 560256, C07C 5136

Patent

active

040524477

ABSTRACT:
Bicycloalkanes of the formula ##STR1## WHEREIN N IS THE INTEGER 1 OR 2; R is methyl or ethyl, and X and Y collectively are a free or ketalized oxo group or X is a hydrogen atom and y is a free, etherified or esterified hydroxy group, are produced by hydrogenating a compound of the formula ##STR2## WHEREIN N, R, X, and Y have the values given above and Me is an alkali metal atom, in an aqueous solution with hydrogen and a palladium-, platinum- or rhodium-containing hydrogenation catalyst. The corresponding free acid is obtained by acidifying the reaction mixture and isolating the reaction product.

REFERENCES:
patent: 3897460 (1975-07-01), Hajos

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