Process for the detection and the qualitative and quantitative d

Chemistry: analytical and immunological testing – Food or dairy products – Wine or alcoholic beverages

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436132, 436139, 436173, 436177, 426592, G01N 2400, G01N 3314

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active

045500827

ABSTRACT:
A process is provided for the detection and qualitative and quantitive differentiation of naturally deuterated molecules.
This process consists in (a) preparing a standard by mixing a commercially available hydrocarbonic product with its artifically deuterated analogue, (b) introducing this standard into the measuring cell of the RMN analysis apparatus; (c) adding the product to be analyzed to the cell and (d) introducing the cell into the RMN (D) apparatus and recording the spectrum of the deuterium which is compared with the RMN (D) spectra of products of known geographical origin and from known chemical and/or biochemical sources, made beforehand with the same standard.

REFERENCES:
patent: 3915641 (1975-09-01), Goering et al.
patent: 4206132 (1980-06-01), Sievers
"Application of Nuclear Magnetic Resonance to Quantitative Analysis of Mixtures of Organic Peroxides, Hydroperoxides, and Alcohols", Ward et al., Analytical Chemistry, vol. 41, No. 3, Mar. 1969, 538-540.
"Organic Chemistry", 3rd Edition Text, Morrison and Boyd, 1973.
Sov. Phys.-Jetp, vol. 42, No. 6, Dec. 1975-"NMR Study of Hydrogen Isotopes to Determine the Ratio of the Proton and Deuteron Magnetic Moments to the Eighth Decimal Place", pp. 950-954.
Z. Naturforsch, vol. 34c, Nov. 2, 1978-Rauschenbach et al.; "Vergleich der Deuterium- und Kohlenstoff-13-Gehalte in Fermentations- und Syntheseethanol", pp. 1-4.
"Manuel de Resonance Magnetique Nucleaire", (1971), R. Freymann et al., pp. 132-137.
C.R. Acad. Sc. Paris, t. 293 (1981), Gerard J. Martin et al., "Chimie Physique Atomique et Moleculaire", pp. 31-33.
European Search Report of EP 82 40 2209.

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