Process for the conversion of calcium sulfide

Paper making and fiber liberation – Processes of chemical liberation – recovery or purification... – With regeneration – reclamation – reuse – recycling or...

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162 35, 423164, 423560, 423DIG3, D21C 1112

Patent

active

057387583

ABSTRACT:
The disclosure relates to a process for the removal of solid CaS from a gas stream in which the CaS has been formed and then the conversion of that solid CaS by reaction with an aqueous NaOH solution to produce solid Ca(OH).sub.2 and a liquor stream containing dissolved NaHS. This removal and conversion process is described as being used in conjunction with a process for gasifying black liquor from a kraft pulping process in which H.sub.2 S is scrubbed from the gases using calcium compounds to form the CaS.

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K. Salmenoja et al., "Development of Black Liquor Gasification", TAPPI Proceedings, 1993 Engineering Conference, pp. 969-975.
R. Backman et al., "Equilibrium behaviour of sodium, sulfur and chlorine in pressurized black liquor gasification with addition of titanium dioxide," Paper and Timber, vol. 76, No. 5, 1994, pp. 320-325.
R.E. Scott-Young et al., "Commercial Development of the DARS Process," 1995 International Chemical Recovery Conference, pp. B263-B267.

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