Process for the chlorine-free bleaching of cellulosic materials

Paper making and fiber liberation – Processes of chemical liberation – recovery or purification... – Gas – vapor or mist contact

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162 78, 162 89, D21C 9153

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active

053465881

ABSTRACT:
A process for the chlorine-free bleaching of pulps in an aqueous suspension which comprises forming the suspension with a consistency of 3 to 20 mass percent; introducing into the suspension an ozone-containing gas having an ozone content of 20 to 300 g/m.sup.3 in an amount corresponding to at most 2 mass percent ozone calculated on dry pulp of the suspension during vigorous agitation of the suspension to form a reaction mixture; maintaining a pressure of the ozone-containing gas at a pressure of 1 to 15 bar during introduction into the suspension; and controlling reaction conditions during contact of the ozone-containing gas with the suspension to maintain a reaction temperature of 15.degree. to 80.degree. and a pH value of 1 to 8.

REFERENCES:
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patent: 4229252 (1980-10-01), Meredith
patent: 4283251 (1981-08-01), Singh
patent: 4310384 (1982-01-01), Meredith et al.
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patent: 4619733 (1986-10-01), Kooi
patent: 4902381 (1990-02-01), Meredith
Osawa et al, "The Action of Gaxous Reagents on Cellulosic Materials", TAPPI, vol. 46, No. 2 pp. 84-89.
Liebergott et al, "The Use of Ozone in Bleaching and Brightening Wood Pulps", Pulping & Bleaching Seminar, New Orleans (Nov. 1978).
Effect of pulp consistency and pH in ozone bleaching by Carl-Anders Lindholm.
Douglas W. Reeve and Paul F. Earl; "Mixing gases, water, and pulp in bleaching"; Jul. 1986 Tappi Journal; pp. 84-88 (Pulp Mixing).
"Effect of Pulp Consistency and pH Inozone Bleaching" Part 3., Carl-Anders Lindholm, Helsinki Univ. of Technology, Espoo, Finland, pp. 44-50.
"Effect of Pulp Consistency and pH in Ozone Bleaching" Part 4, Carl-Anders Lindholm, Paper & Timber Feb. 1989, pp. 145, 147, 149, 150, 152, 154.
"Effect of Pulp Consistency and pH in Ozone Bleaching" Part 2., Carl-Anders Lindholm, 1987 Int. Oxygen Delignification Conf., pp. 155-165.

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