Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge
Patent
1980-06-17
1982-04-13
Prescott, Arthur C.
Chemistry: electrical and wave energy
Processes and products
Electrostatic field or electrical discharge
204130, 204151, 204DIG13, B01D 1302, C25D 2116
Patent
active
043246290
ABSTRACT:
During recyclic use of a chemical copper plating solution, counter anions to copper ions, anions formed by oxidation of a reducing agent, and carbon dioxide by absorption of carbon dioxide from air, which all have an inhibiting effect upon the plating, and also sodium ions having no inhibiting effect are accumulated in the plating solution.
These accumulated ions can be removed by electrodialysis. Particularly, regeneration can be satisfactorily regenerated by adjusting the pH of used chemical plating solution to 2-11 before the electrodialysis, and using a selectively monovalent anion permeable membrane as an anion exchange membrane at the electrodialysis.
REFERENCES:
patent: 3761369 (1973-09-01), Tirrell
patent: 3764503 (1973-10-01), Lancy et al.
patent: 4105532 (1978-08-01), Haines et al.
Kirk-Othmer, Encyclopedia of Chemical Technology, "Electrodialysis", vol. 7, 2nd ed., pp. 849+850 (1965).
Isogai Tokio
Kikuchi Hiroshi
Matsuo Akira
Miyazawa Osamu
Oka Hitoshi
Hitachi , Ltd.
Prescott Arthur C.
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