Process for preparing high cis 3-(2,2,2-trichloroethyl)-2,2-dime

Details Process for preparing high cis 3-(2,2,2-trichloroethyl)-2,2-dime Process for preparing high cis 3-(2,2,2-trichloroethyl)-2,2-dime

1978-02-13

1979-08-28

Raymond, Richard

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260326A, 2603405R, 2603472, 260465D, 560124, 549 76, 549 77, 549 79, 549 60, 549 65, 549 66, C07C 6104, C07D30754

Patent

active

041660641

ABSTRACT:
A process is described whereby esters of 3-(2,2,2-trichloroethyl)-2,2-dimethylcyclopropane-1-carboxylic acid are prepared predominantly in their cis isomer form. The process comprises treating a 4,6,6,6-tetrachloro-3,3-dimethylhexanoate with an alkali metal tert-alkoxide under controlled conditions of temperature in the presence of a defined solvent-cosolvent mixture. The products of the process are intermediates in the production of pyrethroid insecticides.

REFERENCES:
patent: 3077496 (1963-02-01), Julia
Kondo et al., Synthetic Pyrethroids, ACS Symposium Series, No. 42, (1977), Chapter 12.
Itaya et al., Synthetic Pyrethroids, ACS Symposium Series No. 42, (1977), Chapter 4.

Affiliated with

Also associated with

Rating

Process for preparing high cis 3-(2,2,2-trichloroethyl)-2,2-dime does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for preparing high cis 3-(2,2,2-trichloroethyl)-2,2-dime, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for preparing high cis 3-(2,2,2-trichloroethyl)-2,2-dime will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-767492