Process for making glucosone

Chemistry: molecular biology and microbiology – Micro-organism – tissue cell culture or enzyme using process... – Preparing compound containing saccharide radical

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435123, 435148, 435182, 435190, 435813, 435819, C12P 726, C12P 1702, C12P 1902

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043213243

ABSTRACT:
Disclosed are methods of producing glucosone which comprises enzymatically oxidizing glucose with glucose-2-oxidase in a first zone and separating the concomitantly produced hydrogen peroxide from said first zone through a semi-permeable membrane into a second zone wherein an alkene is reacted with said hydrogen peroxide to form oxygenated products of said alkene, said membrane being permeable only to compounds of a molecular weight of less than about 100.

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patent: 4246347 (1981-01-01), Neidleman et al.
patent: 4247641 (1981-01-01), Neidleman et al.
Milas et al., JACS, 58, 1302-1304, (1936).
Milas et al., JACS, 59, 2345-2347, (1937).
Milas et al., JACS, 59, 543-544, (1937).
Milas, JACS, 59, 2342-2344, (1937).

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