Process for functionalizing alkanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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570252, 20415775, 20415773, 20415794, 20415795, B01J 1912, C07C 1700, C07F 1500

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active

047467606

ABSTRACT:
Process for functionalizing saturated hydrocarbons comprising:

REFERENCES:
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Janowicz, A. H. et al. "Activation of C--H Bonds in Saturated Hydrocarbons . . . and Functionalization of the Metal-Bound Alkyl Groups", J. Am. Chem. Soc. 1983, 105, 3929-3939.
Janowicz, A. H. et al. "C--H Activation in Completely Saturated Hydrocarbons: Direct Observation of M+R-H.fwdarw.M(R)(H)", J. Am. Chem. Soc. 1982, 104, 352-354.
Bergman, R. G. "Activation of Alkanes with Organotransition Metal Complexes", Science, Mar. 2, 1984, vol. 223, pp. 902-908.
Janowicz, A. H. et al. "Oxidative Addition of Soluble Iridium and Rhodium Complexes to Carbon-Hydrogen Bonds in Methane and Higher Alkanes", Pure & Appl. Chem., vol. 56, No. 1, pp. 13-23, 1984.
Wax, M. J. et al. "Reversible C--H Insertion . . . and Thermally Activating Methane", J. Am. Chem. Soc. 1984, 106, 1121.
Janowicz, A. H. et al. "Oxidative Addition of Soluble Iridium and Rhodium Complexes to Carbon-Hydrogen Bonds in Alkanes (1)--First IUCCP Symposium, 1983.
Janowicz, A. H. Ph.D. Thesis "A Mechanistic Study . . . Hydrogenolysis of M--C Bonds/C--H Bond Activation of Saturated Hydrocarbons", May 1982.
Periana, R. A. et al. "Rapid Intramolecular Rearrangement . . . Cationic Rhodium .pi.-Allyl Complex", J. Am. Chem. Soc. 1984, 106, pp. 7272-7273.
Periana, R. A. et al. "Oxidative Addition of Rhodium . . . and Alkyl Group Functionalization", Organometallics, 1984, 3, pp. 508-516.
Hoyano, J. K. et al. "Oxidative Addition of the Carbon-Hydrogen Bonds . . . Photochemically Generated Iridium(I) Complex", J. Am. Chem. Soc. 1982, 104, pp. 3723-3725.
Jones, W. D. et al. "Kinetics and Thermodynamics of Intra- and Intermolecular Carbon-Hydrogen Bond Activation", J. Am. Chem. Soc. 1985, 107, 620-631.
Periana, R. A. et al. "Oxidative Addition of Rhodium to Alkane C--H Bonds: Enhancement in Selectivity and Alkyl Group Functionalization", Organometallics, 1984, 3, pp. 508-510.

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