Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material
Patent
1997-08-20
2000-04-25
Niebling, John F.
Semiconductor device manufacturing: process
Coating with electrically or thermally conductive material
To form ohmic contact to semiconductive material
438149, 438151, 438683, 438685, 438655, 438656, 438660, 438663, 438664, H01L 2144
Patent
active
060543868
ABSTRACT:
A nitriding agent is introduced into selected regions of a semiconductor device. A metal such as, for instance, titanium is immediately deposited over the semiconductor device. A subsequent thermal annealing step induces selective reactions between the titanium and the underlying silicon, thereby resulting in the formation of a layer of titanium silicide within the selected regions, as well as a layer of titanium nitride. The layer of titanium nitride and unreacted portions of the layer of titanium are removed in a subsequent etching step, thereby leaving intact a layer of titanium silicide within the selected regions. A second annealing step converts the silicide into a substantially stoichiometric composition. The introduction of the nitriding agent into the selected regions significantly reduces the agglomeration of titanium during silicide formation, thereby resulting in a more uniform, and thus more conductive, silicide layer. In some embodiments, the introduction of the nitriding agent into the selected regions is supplemented by the formation of a layer of silicon-containing material prior to the second annealing step, while in other embodiments the introduction of the nitriding agent is replaced by the formation of the silicon-containing material prior to the second annealing.
REFERENCES:
patent: 5352631 (1994-10-01), Sitaram et al.
patent: 5545574 (1996-08-01), Chen et al.
patent: 5869359 (1999-02-01), Prabhakar
Gurley Lynne A.
Niebling John F.
Paradise, III William L.
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