Coating processes – Coating by vapor – gas – or smoke – Base includes an inorganic compound containing silicon or...
Patent
1991-08-16
1994-01-18
Beck, Shrive
Coating processes
Coating by vapor, gas, or smoke
Base includes an inorganic compound containing silicon or...
4272551, 427337, 427343, C23C 1634, C23C 1646, B05D 304
Patent
active
052798577
ABSTRACT:
A process for forming low resistivity titanium nitride films on a silicon substrate by chemical vapor deposition includes a post-deposition ammonia anneal to provide hydrogen atoms which chemically react with chlorine atoms entrained within the titanium nitride film. The titanium nitride film is deposited by placing the silicon substrate in a reaction chamber, heating the silicon substrate within the reaction chamber, initially passing both TiCl.sub.4 gas and NH.sub.3 gas into the reaction chamber over the silicon substrate to deposit titanium nitride upon a surface of the silicon substrate, and thereafter discontinuing the flow of TiCl.sub.4 gas while continuing to pass NH.sub.3 gas into the reaction chamber over the silicon substrate to react with and remove residual chlorine atoms retained by the deposited titanium nitride film.
REFERENCES:
patent: 2865791 (1958-12-01), Ruppert et al.
patent: 3959557 (1976-05-01), Berry
patent: 4535000 (1985-08-01), Gordon
patent: 4570328 (1986-02-01), Price et al.
patent: 4803127 (1989-02-01), Hakim
X. Xiang, Plasma Chemical Vapour Deposition of TiC, TiC/TiN and Dispersed T.(CN).
Proceedings of the 1986 China-Japan Symposium on Thin Films, Beijing, China Sep. 22-24, 1986.
F. Pintchovski, et al., "LPCVD Titanium Nitride--Deposition, Properties, and Aplication to ULSI", Tungsten and Other Refractory Metals for ULSI Applications, No. IV, 1989, pp. 275-282.
A. Sherman, "Growth and Properties of LPCVD Titanium Nitride as a Diffusion Barrier for Silicon Device Technology", J. Electrochm, Soc., vol. 137, No. 6, Jun. 1990.
S. R. Kurtz et al., "Chemical Vapor Deposition of Titanium Nitride at Low Temperature", Thin Solid Films, 140 (1986), pp. 277-290.
Travis et al. "A Scalable Submicron Contact Technology Using Conformal LPCVD TiN", iIDEM Conference Proceedings, Dec. 1990.
Buiting, et al., "Kinetical Aspects of the LPCVD of Titanium Nitride from Titanium Tetrachloride and Ammonia", J. Electrochem. Soc., vol. 138, No. 2, Feb. 1991, pp. 500-505.
Churley Michael J.
Eichman Eric C.
Sommer Bruce A.
Beck Shrive
Chen Bret
Materials Research Corporation
LandOfFree
Process for forming low resistivity titanium nitride films does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Process for forming low resistivity titanium nitride films, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for forming low resistivity titanium nitride films will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-1135117