Preparation of tris-substituted alkoxycarbonylamino-1,3,5-triazi

Details Preparation of tris-substituted alkoxycarbonylamino-1,3,5-triazi Preparation of tris-substituted alkoxycarbonylamino-1,3,5-triazi

1998-11-10

2000-09-19

Ford, John M.

Organic compounds -- part of the class 532-570 series

Organic compounds

Four or more ring nitrogens in the bicyclo ring system

544197, C07D25170

Patent

active

061214469

ABSTRACT:
The present invention relates to a method for preparing tris-substituted alkoxycarbonylamino-1,3,5-triazine compounds, which involves reacting a amino-1,3,5-triazine compound such as melamine, for example, in the presence of excess amounts of carbon monoxide and an alcohol, a sub-stoichiometric amount of a base, a catalyst system that includes a catalytic amount of a primary catalyst of a group VIII metal or metal salt, and a sub-stoichiometric amount of a co-catalyst of a group I-B or lanthanide series metal or metal salt. The reaction is conducted at a temperature, pressure and length of time sufficient to form a tris-substituted alkoxycarbonylamino-1,3,5-triazine compound in a yield of at least about 5 percent, with improved yields of more than 40 percent being conveniently obtained.

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