Preparation of polyisoprene having high content of 1,2- and 3,4-

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526173, 526209, 5263402, 525244, 525250, 5253331, 525342, 525371, 525914, C08F 448

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048944254

ABSTRACT:
Polyisoprenes having a high content of 1,2- and 3,4-structural units, a process for their preparation, and their use.
The previous processes for the preparation of polyisoprene having a high content of 1,2- and 3,4-structural units were still unsatisfactory in terms of the cocatalyst employed.
The use of ethylene glycol dialkyl ethers of the formula

REFERENCES:
patent: 4118258 (1978-10-01), Graveron et al.
patent: 4385151 (1983-05-01), Furukawa et al.
patent: 4577002 (1986-03-01), Broekhuis
Hirokazu Morita et al., "Isoprene Polymerization by Organometallic Compounds, I," JACS 79, 5853 (1957).

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