Preparation of .alpha.-unsaturated carboxylic esters and amides

Details Preparation of .alpha.-unsaturated carboxylic esters and amides Preparation of .alpha.-unsaturated carboxylic esters and amides

1982-05-17

1984-05-08

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

260410, 2604105, 2604109R, 564132, 560104, C07C 6736, C07C10200

Patent

active

044476400

ABSTRACT:
The invention is a process for preparing .alpha.-unsaturated carboxylic esters or amides comprising contacting a 1,2-dihaloalkane, an alcohol or amine, and carbon monoxide, in the presence of a catalytic amount of a group VIII metal at elevated temperatures and pressures. The invention further includes preventing the .alpha.-unsaturated carboxylic esters or amides prepared by the addition of a free radical inhibitor capable of improving catalyst lifetime to the reaction mixture.

REFERENCES:
patent: 2210563 (1940-08-01), Andrussow
patent: 2765350 (1956-10-01), Conrad
patent: 3457299 (1969-07-01), Closson et al.
patent: 3626005 (1971-12-01), Scheben et al.
patent: 3927131 (1975-12-01), Ward
patent: 3988358 (1976-10-01), Heck
Scheben, John A. et al., Catal. Org. Syn., (Conf. 5th), pp. 181-201, (1975).
Kirk-Othmer Encyclopedia of Chemical Technology, 2nd Ed., vol. 13, (1967), 333, 348 and 349.
Heck, R. F. Advances in Catalysis, vol. 26, (1977), pp. 323-347.
Mitsubishi Rayon Co. Chemical Abstracts, vol. 71, (1969), No. 49317p, (French Pat. 1,541,977).
Yamagishi, Akio et al. Chemical Abstracts 75, (1971), No. 21744j.
Sato, Ryozi et al. Chemical Abstracts 76, (1972), No. 3403p.
Kawamura, Yuichi et al. Chemical Abstracts 76, (1972), No. 60282.
Sugita, Shigeski et al. Chemical Abstracts, vol. 83, (1975), No. 192582g.
Shimizu, Noboru et al. Chemical Abstracts, vol. 84, (1978), No. 18032f.
Sudo, Makoto et al., Chemical Abstracts, vol. 84, (1976), No. 90761k.
Ohtani, Mitsuo et al. Chemical Abstracts, vol. 88, (1978), No. 51330g.
Firsov et al. Chemical Abstracts, vol. 90, (1979), No. 169288u.

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