Preparation of alkylhalosilanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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C07F 716

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active

058471812

ABSTRACT:
An alkylhalosilane is prepared by charging a reactor with a contact mass comprising metallic silicon powder and a copper catalyst and feeding a reactant gas containing an alkyl halide into the reactor whereby the silane is formed by direct synthesis. A phosphorus compound is added to the contact mass in an amount of 3,000-10,000 ppm calculated as phosphorus. The invention produces a more amount of dialkyldihalosilane in a desirable STY while minimizing the amount of unnecessary disilanes.

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patent: 5068385 (1991-11-01), Degen et al.

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