Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...
Patent
1992-12-08
1994-10-11
Kight, III, John
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
At least one aryl ring which is part of a fused or bridged...
524838, 528 26, 528 28, 528901, 525453, 525459, C08G 1812
Patent
active
053548086
ABSTRACT:
Ungelled, aqueous dispersions of silane-terminated partially crosslinked polyurethane polymers are described which are the reaction product of A) an isocyanate-containing prepolymer formed from: (i) a molar excess of organic polyisocyanate sufficient to promote substantially equal access to isocyanate groups; (ii) active hydrogen-containing material; (iii) sterically hindered amines; (iv) emulsifying monomer; B) chain-extending monomer; C) an organic compound having a pKb of at most about 7; and D) a silane coupling agent represented by the general formula ASi(OR.sup.2).sub.3 and present in an amount sufficient to partially crosslink the polyurethane resin but insufficient to gel the dispersion, provide advantages over previously known polyurethanes used as surface coatings. The hindered amine allows surface coatings incorporating the polyurethanes to be easily removed by aqueous compositions having pH between about 2 and 5. Methods of making the prepolymers, polymers, and dispersions are also presented.
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Frisch, Jr. Kurt C.
Onwumere Fidelis C.
Griswold Gary L.
Johnson Rachel
Kight III John
Kirn Walter N.
Minnesota Mining and Manufacturing Company
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