Polymers and photoresist compositions for short wavelength...

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

Reexamination Certificate

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C430S325000, C430S326000, C430S905000, C430S907000, C430S910000

Reexamination Certificate

active

09948526

ABSTRACT:
This invention relates to resins and photoresist compositions that comprise such resins. Preferred polymers of the invention comprise adjacent saturated carbon atoms, either integral or pendant to the polymer backbone, that have a substantially gauche conformation. Polymers of the invention are particularly useful as a resin binder component of chemically-amplified positive-acting resists that can be effectively imaged at short wavelengths such as sub-200 nm and preferably about 157 nm. In such short-wavelength imaging applications, polymers of the invention that have a population of dihedral angles of adjacent saturated carbon atoms that are enriched in substantially gauche conformations can provide reduced undesired absorbance of the high energy exposure radiation.

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S.-J. Choi et al.: “Design and Synthesis of New Photoresist Materials for ArF Lithography” Proceedings of the SPIE—The International Society for Optical Engineering, vol. 3999, No. 1, Mar. 1, 2000, pp. 54-61, XP002193478, USA, p. 56.
H.-W. Kim et al., “Novel Polymers for 193 nm Single Layer Resist Based on Cycloolefin Polymers”, Proceedings of the SPIE—The International Society for Optical Engineering, vol. 3999, No. 2, Mar. 1, 2000; pp. 1100-1107, XP002193479, USA, p. 1101; Figure 2.
J.-B. Kim et al., “Chemically Amplified Resists Based on the Norbornene Copolymers with Steroid Derivatives”, Proceedings of the SPIE—The International Society for Optical Engineering, vol. 3678, No. 1, Mar. 17, 1999, pp. 36-43, XP002179488 USA, p. 38, Figure 2.
T. Aoai et al., “Structural Design of New Alicyclic Acrylate Polymer with Androstane Moiety for 193 nm Resist”, Proceedings of the SPIE—The International Society for Optical Engineering, vol. 3678, No. 1, Mar. 17, 1999, pp. 283-293, XP000997830, USA p. 292; Figure 7.

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