Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymerizing in reactor of specified material – or in reactor...
Patent
1994-01-13
1996-01-16
Schofer, Joseph L.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymerizing in reactor of specified material, or in reactor...
526 74, C08F 200
Patent
active
054848555
ABSTRACT:
A polymer scale preventive process for use in polymerization of a monomer having an ethylenically unsaturated double bond, comprising an alkaline solution containing (A) a condensation product of (A-1) an aromatic compound having at least two amino groups with (A-2) an aromatic tetracarboxylic acid anhydride, and (B) at least one member selected from the group consisting of (B-1) a water-soluble polymeric compound and (B-2) an inorganic colloid. The scale preventive process is low in virulence or the like, and high in safety. The process is used for forming a coating on inner wall surfaces of a polymerization vessel. Where such a polymerization vessel is used to carry out the polymerization, polymer scale deposition can be effectively prevented, not only on areas in the liquid-phase region but on areas around the gas-liquid interface in the vessel, and the resulting polymeric product shows few fish eyes and good whiteness when formed into sheets or the like.
REFERENCES:
patent: 4081248 (1978-03-01), Cohen
patent: 5115051 (1992-05-01), Shimizu et al.
Shimizu Toshihide
Watanabe Mikio
Schofer Joseph L.
Shin-Etsu Chemical Co. , Ltd.
Weber Tom
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