Photopolymerizable composition

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Radiation sensitive composition or product or process of making

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20415918, 20415923, 430283, 430284, 430285, 430919, G03C 168

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active

042398509

ABSTRACT:
A photopolymerizable composition comprising a polymerizable ethylenically unsaturated compound, optionally, a linear organic polymer, and a photopolymerization initiator comprising a combination of a compound represented by the general formula (I) ##STR1## wherein Z represents the non-metal atomic group necessary to form a nitrogen containing heterocyclic nucleus, R.sub.1 represents an alkyl group or a substituted alkyl group, and R.sub.2 represents an alkyl group or an aryl group having a comparatively high photopolymerization initiating ability; and a compound represented by the general formula (II) ##STR2## wherein X represents a halogen atom, Y represents --CX.sub.3, --NH.sub.2, --NHR.sup.1, --NR.sup.1.sub.2 or OR.sup.1, R.sup.1 represents an alkyl group or an aryl group and R represents an alkyl group, an alkyl group substituted with at least one chlorine atom, an aryl group, a substituted aryl group or a substituted alkenyl group.

REFERENCES:
patent: 3870524 (1975-03-01), Watanabe et al.
patent: 3954475 (1976-05-01), Bonham et al.
patent: 3961961 (1976-06-01), Rich
patent: 4058398 (1977-11-01), Ogada et al.
patent: 4058443 (1977-11-01), Murata et al.
Wakabayshi, et al., Bull. Soc. Japan, 42, 2924 (1969).
Schaefer et al., J. Org. Chem., 29, 1527 (1964).

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