Pesticidal compositions comprising ethoxylated citric or tartari

Details Pesticidal compositions comprising ethoxylated citric or tartari Pesticidal compositions comprising ethoxylated citric or tartari

1991-03-07

1993-12-28

Raymond, Richard L.

Plant protecting and regulating compositions

Plant growth regulating compositions

424405, 514521, 514531, A01N 2522

Patent

active

052739538

DESCRIPTION:

BRIEF SUMMARY
The invention relates to plant protecting preparations, veterinary preparations and additive preparations admixable with plant protecting and veterinary preparations containing as surface active agents compounds of the formulae (I) ##STR2## The invention also relates to the preparation of such composition. The meaning of the substituents in the formulae (I) and (II) are as follows: inorganic cation, or a group of the formula --(CH.sub.2 CH.sub.2 --O).sub.n R.sup.1, wherein
The inorganic cation is advantageously a sodium potassium, calcium or magnesium cation. The organic cation is advantageously a cation deriving from an amine, such as triethanolamine or diethanolamine.
The surface active agents of the formulae (I) and (II) used in the preparations according to the invention and their use in cosmetic and detergent therapeutical preparations is disclosed in the published Hungarian Patent specification T/40994.
The compounds of the formulae (I) and (II) can be prepared by ethoxylating a fatty alcohol corresponding to R.sup.1 (mean ethyleneoxide number is n), whereafter it is condensed with citric or tartaric acid and finally a salt is formed as required with an alkaline component supplying the suitable cation (published Hungarian Patent Specification T/40994).
We have found that the surface active agents of the formulae (I) and (II) can be advantageously used in plant protecting and veterinary preparations, respectively.
According to the invention from the surface active agents of the formulae (I) and (II) also additive preparations without any active ingredient can be prepared, which can be admixed at the time of application with the plant protecting or veterinary preparation to be applied.
The surface active agents of the formulae (I) and (II) exert in the preparations according to the invention the following positive effects: thus exert a stabilizing effect; modification); the stability of the dispersion; advantageous from the view-point of the dispersion of active ingredient and stability of the preparation; suitable for the penetration of capsules; ingredients, etc.; and poisonous effect and, biologically they are totally decomposable (a biodegradation of 100%).
The preparations according to the invention contain the surface active agents of the formulae (I) and (II) in the following amounts:


______________________________________ plant protecting preparations 0.1-10 mass % veterinary preparations 0.1-10 mass % additive preparations 0.1-50 mass % ______________________________________
The plant protecting preparations according to the invention may contain as active ingredient some fungicidal, herbicidal, insecticidal, nematocidal, acaricidal or plant growth regulating agents, such as: with zinc salt] [N-(3,5-dichlorophenyl)-1,2-dimethyl-cyclo-propane-1,2-dicarboximide] (RS)-2,4'-difluoro-.alpha.-(1H-1,2,4-triazole-1-yl-methyl)-benzhydryl-alco hol N,N-dimethyl-N'-phenyl-N'-(fluoro-dichloro-methyl-thio)-sulphamide 3-(3,5-dichloro-phenyl)-5-methyl-vinyl-1,3-oxazolidine-2,4-dione 2-(0,0-diethyl-thiophosphoryl)-5-methyl-6-carbethoxy-pyrazolo-(1,5-a)-pyri midine .alpha.-(2-chloro-phenyl)-.alpha.-(4'-chloro-phenyl)-5"-pyrimidyl-methanol 1-[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolane-2-yl-methyl]-1H-1,2,4-tri azole 1-(4-chloro-phenoxy)-1-(1H-1,2,4-triazole-1-yl)-3,3-dimethyl-2-butanone 1-(4-chloro-phenoxy)-1-(1H-1,2,4-triazole-1-yl)-3,3-dimethyl-2-butanol .beta.-(1,1'-biphenyl-4-yl-oxy)-.beta.-(1,1-dimethyl-ethyl)-1H-triazole-1- ethanol 1-(2,4-dichloro-phenyl)-4,4-dimethyl-2-(1,2,4-triazole-1-yl)-pentane-3-ol 4-(3-[4-(1,1-dimethyl-ethyl)-phenyl]-2-methyl)-propyl-2,6-cis-dimethylmorp holine D,L-N-(2,6-dimethyl-phenyl)-N-(2'-methoxyacetyl)-alanine-methyl-ester N-propyl-N-[2-(2,4,6-trichloro-phenoxy)-ethyl]-imidazole-1-carboxamide (.+-.)-cis,transz-3-3(2,2-dichloro-vinyl)-2,2-dimethyl-cyclopropanic acid-3-phenoxy-benzyl-ester acid-(.alpha.-cyano-3-phenoxybenzyl)-ester carboxylic acid-(S)-.alpha.-cyano-m-phenoxy-benzyl-ester (2-methyl)-1,1'-biphenyl(-3-il)methyl-3-(2-chloro-3,3,3-trifluoro-1-prop

REFERENCES:
patent: 3898075 (1975-08-01), Freund et al.
patent: 4048065 (1977-09-01), Suen et al.
patent: 4668507 (1987-05-01), Tomkins et al.
patent: 4673509 (1987-06-01), Davis et al.
patent: 5043163 (1991-08-01), Pap et al.
patent: 5082591 (1992-01-01), Marchetto et al.
Spencer, E. Y. Guide to Chemicals Used in Crop Protection Research Branch, Agriculture Canada, 1981, p. 152.

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