Pb.sub.1-W Cd.sub.W S Epitaxial thin film

Metal treatment – Barrier layer stock material – p-n type – With non-semiconductive coating thereon

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148 334, 148 335, 148175, 252 623ZT, 357 61, 423518, H01L 2926, H01L 2712

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active

042820456

ABSTRACT:
A variable temperature method for the preparation of single and multiple epitaxial layers of single-phase (e.g., face-centered cubic), ternary lead chalcogenide alloys (e.g., lead cadmium sulfide, [Pb.sub.1-w Cd.sub.w ].sub.a [S].sub.1-a wherein w varies between zero and fifteen hundredths, inclusive, and a=0.500.+-.0.003), deposited upon substrates of barium fluoride, BaF.sub.2, maintained in near thermodynamic equilibrium with concurrently sublimated lead alloy and chalcogenide sources. During preparation, the temperature of the substrate is varied, thereby providing an epilayer with graded composition and predetermined electrical and optical properties along the direction of growth. This growth technique can be used to produce infrared lenses, narrowband detectors, and double heterojunction lasers.

REFERENCES:
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patent: 3716424 (1973-02-01), Schoolar
patent: 3793070 (1974-02-01), Schoolar
patent: 3969743 (1976-07-01), Gorski
patent: 3985918 (1976-10-01), Fukai et al.
patent: 4053919 (1977-10-01), Andrews et al.
patent: 4066481 (1978-01-01), Manasevit et al.
Walpole et al., "Single Heterojunction PbSmTe Diode Lasers," Applied Phys Letters, vol. 23, No. 11, 1 Dec. 1973, pp. 620-622.

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