Chemistry of inorganic compounds – Nitrogen or compound thereof – Oxygen containing
Patent
1984-06-14
1985-04-23
Doll, John
Chemistry of inorganic compounds
Nitrogen or compound thereof
Oxygen containing
C25D 352
Patent
active
045129630
ABSTRACT:
The invention is a process for electroplating palladium in which at least part of the palladium in the electroplating bath is added as a palladium ammine hydroxide. Both the solid form and solution form of palladium ammine hydroxide are useful in supplying palladium to the palladium electroplating bath. Both solution and crystals are chemically stable and can be stored for long periods of time. Further, use of the palladium ammine hydroxide compounds permit replenishment without accumulation of undesirable ions in the bath and also neutralizes hydrogen ions formed in the plating process.
REFERENCES:
patent: 2452308 (1948-10-01), Lambros
patent: 4377450 (1983-03-01), Okinaka
Patent Application Abys-Trop 1-1 Ser. No. 239,151, filed Feb. 27, 1982.
Canadian Journal of Chemistry, vol. 50, "Hydroxy Complexes of Platinum (II) and Palladium (II)", pp. 3694-3699, (1972).
Encyclopedia of Electrochemistry, C. A. Hampel pp. 448-456, and 726-735, (1964).
Abys Joseph A.
Okinaka Yutaka
AT&T Bell Laboratories
Doll John
Langel Wayne A.
Nilsen Walter G.
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