Oxygen concentration sensing apparatus

Chemistry: electrical and wave energy – Processes and products – Vacuum arc discharge coating

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Details

60276, 123489, G01N 2758

Patent

active

043138101

ABSTRACT:
An oxygen concentration sensing apparatus in which a block of an oxygen-ion conductive solid electrolyte is interposed between a first electrode and a second electrode disposed opposite to each other. The first electrode is made of a catalytic metal and is exposed at a portion thereof on a surface of the solid electrolyte block, and an electrical insulating heat-resistive layer having a plurality of communication pores covers the exposed portion of the first electrode. The second electrode is porous and made of a catalytic metal. The solid electrolyte is wholly exposed to a stream of gases containing oxygen whose concentration is to be measured, and during measurement, a current source supplies continuously an electric current in a direction from the first electrode toward the second electrode. When the partial pressure of oxygen gas produced at the first electrode and existing in the vicinity thereof exceeds a predetermined value, the excess pressure portion of oxygen gas is discharged into the stream of gases through the communication pores of the heat-resistive layer thereby maintaining substantially constant the partial pressure of oxygen gas in the vicinity of the first electrode. An electromotive force representing the ratio between the partial pressure of oxygen around the first electrode and that in the stream of gases containing oxygen is measured to determine the concentration of oxygen contained in the gases.

REFERENCES:
patent: 4207159 (1980-06-01), Kimura et al.

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