Oxidative dehydrogenation of olefins over a high activity cobalt

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260680E, C07C 1510, C07C 1112

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active

040026965

ABSTRACT:
There is disclosed a method comprising the oxidative dehydrogenation of at least one hydrocarbon selected from the group consisting of butene-1, butene-2, 2-methyl-1-butene, 2-methyl-2-butene, 3-methyl-1-butene, n-pentene, 2,3-dimethyl-1-butene, 2,3-dimethyl-2-butene, 2-methyl-1-pentene, 2-methyl-2-pentene, 4-methyl-2-pentene, 3-methyl-1-pentene, 3-methyl-2-pentene, 2-ethyl-1-butene, ethyl benzene and isopropyl benzene at oxidative dehydrogenation conditions while in the presence of a catalyst comprising cobalt-molybdate which has enhanced activity by being calcined at temperatures from 750.degree.-1100.degree. C for at least one hour prior to use in the oxydehydrogenation process.

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patent: 3692860 (1972-09-01), Boutry et al.
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patent: 3894055 (1975-07-01), Farha et al.
patent: 3917736 (1975-11-01), Frech et al.

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