Oxidation structure/method to fabricate a high-performance...

Semiconductor device manufacturing: process – Having magnetic or ferroelectric component

Reexamination Certificate

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C438S238000, C438S381000

Reexamination Certificate

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06974708

ABSTRACT:
An MTJ (magnetic tunneling junction) MRAM (magnetic random access memory) has a tunneling barrier layer of substantially uniform and homogeneous Al2O3stoichiometry. The barrier layer is formed by depositing Al on a CoFe layer or a CoFe—NiFe bilayer having an oxygen surfactant layer formed thereon, then oxidizing the Al by radical oxidation. The underlying surfactant layer contributes oxygen to the bottom surface of the Al, forming an initial amorphous Al2O3layer. This layer produces small, uniform grains in the remaining Al layer, which promotes a uniform oxidation of the Al between its upper and lower surfaces by the subsequent radical oxidation. A final annealing process to set a pinned layer magnetization enhances the homogeneous oxidation of the layer.

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patent: 6703654 (2004-03-01), Horng et al.
patent: 2002/0081753 (2002-06-01), Gates et al.
patent: 2005/0003561 (2005-01-01), Drewes
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Copending U.S. Appl. No. 10/768,917, filed Jan. 30, 2004, to Horng et al., “A Novel-Oxidation Method to Fabricate Low Resistance TMR Read Head”.
Copending U.S. Appl. No. 10/661,038, filed Sep. 12, 2003, to Horng et al., “Process and Structure to Fabricate Spin Valve Heads for Ultra-High Recording Density Application”.
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Copending U.S. Appl. No. 10/849,310, filed May 19, 2004, to Horng et al., “A Novel Buffer (Seed)Layer for Making a High-Performance Magnetic Tunneling Junction MRAM”.

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