Oxidation of primary alcohols to aldehydes using transition meta

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568594, 568487, C07C 4529, C07C 4156

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active

051324652

ABSTRACT:
Primary alcohols may be oxidized to the corresponding aldehydes using non-toxic oxidizing agents such as tert-butyl hydroperoxide (TBHP) in the presence of a transition metal phthalocyanine catalyst. Representative catalysts include ferrous phthalocyanine and chloroferric phthalocyanine. Under some conditions, 1,1-dialkoxyalkanes may be co-produced with the aldehydes. 1,1-Dialkoxyalkanes are protected aldehydes and find utility in solvents.

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