Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...
Patent
1978-12-04
1980-09-16
Marquis, Melvyn I.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From silicon reactant having at least one...
260 292M, 260 334SB, 427387, 428412, 428447, C08G 7706
Patent
active
042231213
ABSTRACT:
A process for forming organopolysiloxanes from trialkoxysilanes and the resulting resinous products are disclosed, characterized in that the organopolysiloxane resins have increased hardness when hydrolysis and condensation of the trialkoxysilanes are carried out in aqueous solution acidified by formic acid and at a relatively high strength previously regarded as inoperative. The formic acid, for example, may be present in an amount greater than 700 ppm. After hydrolysis of the trialkoxysilane, the resulting silonetriol is condensed to form the organopolysiloxane.
REFERENCES:
patent: 3457221 (1969-07-01), Stengle, Jr.
patent: 3460980 (1969-08-01), Burzynski
patent: 3474070 (1969-10-01), Levene
patent: 3491054 (1970-01-01), Thomas
patent: 4006271 (1977-02-01), French et al.
Morrison et al., Organic Chemistry, p. 454, Allyn and Bacon, Inc., Boston (1959).
Birchall David R.
Click Myron E.
Marquis Melvyn I.
Owens--Illinois, Inc.
Wilson David H.
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