Oligomerizing 1-olefins with a heterogeneous catalyst

Details Oligomerizing 1-olefins with a heterogeneous catalyst Oligomerizing 1-olefins with a heterogeneous catalyst

1981-12-22

1982-12-21

Gantz, Delbert E.

Chemistry of hydrocarbon compounds

Unsaturated compound synthesis

By addition of entire unsaturated molecules, e.g.,...

585510, C07C 202

Patent

active

043651054

ABSTRACT:
An alpha-olefin is oligomerized in the presence of a three-component catalyst comprising a particulate solid adsorbent, boron trifluoride and elemental oxygen. For example, 1-decene is oligomerized to a product predominating in the trimer and tetramer using boron trifluoride, elemental oxygen and silica as the solid adsorbent.

REFERENCES:
patent: 2568209 (1951-09-01), Wackher et al.
patent: 4213001 (1980-07-01), Madgaukar et al.

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