Oligo(2-alkenyl azlactones)

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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540471, 540479, 544 71, 544 96, 544 72, 548216, 548225, C08F12606

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active

050811975

ABSTRACT:
This invention provides novel azlactone-functional oligomers of 2-alkenyl azlactones in which oligomerization has occurred predominantly via the 2-alkenyl group. Oligomerization of the 2-alkenyl group provides oligomers having 2 to 15 mer units with predominantly carbon-carbon backbone segments. Oligomerized in this fashion, the novel compositions possess azlactone groups which can be reacted with nucleophiles in the normal ring-opening sense. The oligomers are prepared by a novel process in which both Lewis and Bronsted acidic catalysts are effective. The reactive oligomers find utility as crosslinking agents for polymers containing azlactone-reactable nucleophilic groups.

REFERENCES:
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Rasmussen, J. K. et al., "Polyazlactones", Encyclopedia of Polymer Science and Engineering, vol. 11, 2nd Ed. John Wiley & Sons, Inc: NY, 1988, pp. 558-571.
Greeley, R. Z., "Q and e Values for Free-Radical Copolymerization of Vinyl Monomers & Telogens", Polymer Handbook, Edited by J. Brandup & E. H. Immerhut, 3rd Ed., John Wiley & Sons, Inc.: NY, 1989, II-267 to II-274.

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