Novel radiation curable coating compositions for pressure-sensit

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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106 21, 106 28, 106 32, 260 23AR, 260 318R, 260 318XA, 260 336UA, 260 336R, 260 338R, 260 338UA, 282 275, 428914, C08L 9100

Patent

active

041861159

ABSTRACT:
A novel chromogenic composition is produced comprising at least one color precursor dissolved in a carrier oil, the carrier oil being a weakly polar solvent having a boiling point of from about 180.degree. C. to about 300.degree. C., the color precursor being of the electron donor type and being reactive with color developers of the electron acceptor type to form an image and a liquid radiation curable substance, the liquid radiation curable substance being selected from the group consisting of isocyanate modified acrylic, methacrylic and itaconic acid esters of polyhydric alcohols, acrylic prepolymers derived from partial esterification of pentaerythritol with acrylic acid and acrylic acid esters and mixtures thereof, the liquid radiation curable substance being curable to a frangible resin upon exposure to radiation. The coating composition has a viscosity in the range of about 1000 cps. to about 3500 cps. A pressure-sensitive, carbonless transfer sheet is produced comprising a paper substrate having coated thereon a barrier layer and a cured resinous film coated on said barrier layer, the cured resinous film being a radiation cured film of the novel chromogenic coating composition having a frangibility that will permit passage of the color precursor and the carrier oil to the surface of the cured resinous film when the cured resinous film is broken, the color precursor solution being retained as small occlusions within a matrix of closely packed cross-linked molecular chains of cured resin.

REFERENCES:
patent: 3020170 (1962-02-01), Macaulay
patent: 3720534 (1973-03-01), Macaulay et al.
patent: 3754966 (1973-08-01), Newman et al.
patent: 4091122 (1978-05-01), Davis et al.
patent: 4112138 (1978-09-01), Davis et al.

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