Nonvolatile semiconductor memory and method of fabrication

Active solid-state devices (e.g. – transistors – solid-state diode – Field effect device – Having insulated electrode

Reexamination Certificate

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C257S314000, C257S315000, C257S322000, C438S201000, C438S211000, C438S257000

Reexamination Certificate

active

06335553

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a nonvolatile semiconductor memory and, more particularly, to a contactless, nonvolatile, metal oxide semiconductor (MOS) memory, and also to a method of fabricating the device.
2. Discussion of the Related Art
The fundamental structure of a conventional nonvolatile MOS memory cell is briefly described below with reference to
FIG. 1
, a sectional view of a simplified nonvolatile MOS memory cell with a stacked, floating gate configuration. More realistic configurations differ from the simplified configuration of
FIG. 1
primarily in the shape and positioning of the gates.
As shown in
FIG. 1
, thin tunneling (gate) oxide
2
separates conductive floating gate
3
(the term floating gate refers to the fact that no electrical conductor is connected to this gate) and the channel of lightly-doped, p-type semiconductor substrate
1
. Thick oxide
4
separates control gate
5
and the floating gate. Heavily-doped, r-type source/drain regions
6
lie within the substrate to either side of the floating gate
The nonvolatile MOS memory cell illustrated in
FIG. 1
may be viewed as simply a conventional MOS field effect transistor whose gate structure has been modified so as to enable semipermanent charge storage on the gate. The stacked, floating gate configuration is simply one technology by which charge retention on the gate has been realized. The charge stored on the gate gives rise to a threshold voltage shift, so that a nonvolatile, MOS memory with stored charge is at a higher-threshold-voltage state than the device with no stored charge. An impressed gate voltage, ultraviolet light, or some other technology may be used to eliminate the stored charge and return the device to its lower-threshold-voltage state. The charge-transfer mechanism of nonvolatile memory cells whose structures may be illustrated by
FIG. 1
is based on tunneling through the thin gate oxide rather than on avalanche injection of hot electrons from the channel to the floating gate.
Nonvolatile MOS memory cells which have a stacked, floating gate configuration are favored for high-density applications due to their characteristically small cell sizes. Absent other changes, any reduction in cell size is necessarily accompanied by a decrease in the capacitive coupling between the control gate and the floating gate. To mitigate this effect of the reduction in cell size, a silicon dioxide/silicon nitride/silicon dioxide (ONO) composite dielectric, which has a higher breakdown voltage than a single oxide film, may be used as the insulator between the floating and control gates. The enhanced inter-gate capacitance due to use of an ONO dielectric comes at the price of the several processing steps, including a high temperature annealing, required to form the ONO sandwich, which result in a higher manufacturing cost and lower device yield per wafer.
Research is also continuing into the use of materials such as tantalum pentoxide, which has a significantly higher dielectric constant than silicon dioxide, as the insulator between the floating and control gates. At present, however, novel memory cell structures, rather than novel materials, appear to offer the most likely way to increase capacitive coupling while reducing effective memory cell size.
Since a conventional stacked, floating gate MOS memory device requires one metal contact for every two cells of the memory cell array, the size of an array of N stacked, floating gate memory cells is significantly greater than N times the size of a single memory cell. So-called contactless, nonvolatile memory cell technologies have been developed to counter this increase in effective cell size. A conventional contactless memory cell is described immediately below with reference to
FIG. 2
, a plan view of a contactless, nonvolatile MOS memory cell array, and
FIG. 3
, a sectional view of the device of
FIG. 2
along line I-I′.
As shown in
FIGS. 2-3
, regularly-spaced, parallel pairs of heavily-doped, n-type source/drain regions
12
lie within a lightly-doped, p-type semiconductor substrate
11
. A thin, tunneling dielectric film
17
, typically a thermal oxide, covers the upper surface of the substrate. Insulating structures
15
isolate the source region of each of the above pairs of heavily-doped regions from the drain region of an adjacent pair of heavily-doped regions, and vice versa.
Regularly spaced, parallel, conductive control gates
13
above the substrate are perpendicular to the heavily-doped source/drain regions
12
. Below any given control gate lie a plurality of conductive floating gates
14
on the dielectric film
17
, each of which spans the interval between the members of one of the above pairs of source/drain regions. Insulating dielectric film
16
separates any given control gate from the floating gates below that control gate.
The memory device illustrated by
FIGS. 2-3
includes a rectangular array of memory cells, each of which includes a single floating-gate, MOS transistor. The cells are interconnected by the control gates
37
extending along the row direction of the array and by the heavily-doped source/drain regions
12
extending along the column direction of the array. Each control gate serves as a word-line of the memory array, since it controls the movement of a bit into or out of the group of memory cells to which it is connected; the heavily-doped drain regions
12
serve as bit-lines of the array, since each transmits that bit to the rest of the system. The heavily-doped drain regions can serve as bit-lines due to their low bulk resistivity, so that metal lines need not be fabricated to serve this function. -More importantly, the use of the heavily-doped drain regions as bit-lines means that a separate metal contact need not be formed to connect each memory cell to a bit-line, which results in a reduced effective memory cell size.
Although the contactless, nonvolatile memory cell array illustrated by
FIGS. 2-3
is characterized by a relatively large capacitive coupling between the control gate and the floating gate, the isolating structures
15
which serve to isolate any memory cell in the array from the memory cells adjacent to it significantly increase the effective size of a memory cell.
U.S. Pat. No. 5,047,362, which issued on Sept. 10, 1991 to Albert Bergemont for Method for Making Large-Scale EPROM Memory with a Checker Board Pattern and an Improved Coupling Factor, which is hereby incorporated by reference in its entirety, discloses a contactless, nonvolatile memory which is characterized by relatively large intergate capacitive coupling but which does not employ insulating structures to isolate the memory cells of the array from each other. Such a memory array is described below with reference to
FIG. 4
, a plan view of the device, and
FIG. 5
, a sectional view of the device of
FIG. 4
along line II-II′.
The nonvolatile memory device illustrated in
FIGS. 4-5
comprises a matrix of memory cells interconnected by word-lines extending along the row direction of the matrix and bit-lines extending along the column direction of the matrix. Each memory cell comprises a symmetrical pair of floating-gate, MOS field effect transistors of the same row that share a common drain. Each of the two sources of a given memory cell is in turn shared with a transistor of an adjacent memory cell of the same row.
The memory cells are interconnected by the control gates
13
(word-lines) extending in the row direction of the matrix and by the heavily-doped drain regions
12
b
(bit-lines) extending along the column direction of the matrix. Heavily doped regions
12
a
and
12
c
adjacent to the heavily-doped region
12
b
between them serve as source regions. Regularly-spaced, parallel triplets of heavily-doped, n-type source/drain regions
12
a
,
12
b
, and
12
c
lie within lightly-doped, p-type semiconductor substrate
11
. Thin tunneling oxide
17
covers the upper surface of the substrate.
Regularly-spaced, conductive first floating gates
14
a
,

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