NADH.sub.2 mimics as chiral pseudohydrogenases

Details NADH.sub.2 mimics as chiral pseudohydrogenases NADH.sub.2 mimics as chiral pseudohydrogenases

1985-02-08

1986-09-30

Kight, John

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Mixing of two or more solid polymers; mixing of solid...

525375, 260684, 526259, 526265, 435183, 435188, 435193, 435189, C08F 2606

Patent

active

046147691

ABSTRACT:
A broad class of polymers which mimic the NAD--NADH.sub.2 couple is disclosed. These polymeric pseudohydrogenases may be used to asymmetrically reduce many types of carbonyl, thiocarbonyl, and imino groups in either a batch or continuous process, with the absolute configuration of the resulting optically active product predictable from the known absolute configuration of the chiral polymer.

REFERENCES:
patent: 4011204 (1977-03-01), Benes et al.
Talma et al, "Reduction of Activated Carbonyl Compounds with Bridges 1,4-Dihydropyridine", J. Am. Chem. Soc. 1985, vol. 107, pp. 3981-3997.
Chem. Abst. #109143e, vol. 85, 1976, Tahedena et al, Kinetics of the Acylation of an Oxime Group . . . N-Methyl-4-Vinylpyridium-Cl".
Kurimura et al, Effect of the Polymeric Ligand on Electron-Transfer Reaction," J. Polymer Science, vol. 9(12) 1971, pp. 3521-3527.

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