N-type oxide superconductor represented by the formula (Nd.sub.x

Superconductor technology: apparatus – material – process – High temperature – per se – Having tc greater than or equal to 150 k

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505800, 505801, 505809, 505810, 505775, 505779, 505123, 505126, 252518, 252521, 423593, H01L 3912, C01G 302, C04B 3550

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active

052448711

ABSTRACT:
An oxide superconductor comprises a composition represented by the composition formula: (Nd.sub.x --Ce.sub.y --L.sub.z).sub.2 CuO.sub.4-d (wherein L is an element selected from Ca and Mg, and x+y+z=1). The compositions of Nd, Ce and L of the oxide superconductor corresponds to a point falling inside an area of Nd--Ce--L ternary diagram surrounded by straight lines (A-B), (B-C), (C-D) and (D-A) connecting point (A) with point (B), point (B) with point (C), point (C) with point (D) and point (D) with point (A), respectively, the points (A), (B), (C) and (D) being points (x=1, y=0, z=0), (x=0.4, y=0.6, z=0), (x=0.4, y=0.3, z=0.3) and (x=0.1, y=0, z=0.9), respectively, in the Nd--Ce--L ternary diagram. Above-described Nd--Ce--L--Cu--O oxides can exhibit superconductivity within a wide range of composition when heat-treated in an atmosphere of nitrogen.

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Sawa et al., "A New Family of Superconducting Copper Oxides: (Ln.sub.1-x Ce.sub.x).sub.2 (Ba.sub.1-y Ln.sub.y).sub.2 Cu.sub.3 O.sub.10-.delta. (Ln: Nd, Sm, Eu)" Jrnl Phys Soc Jap vol. 58, No. 7 pp. 2252-2255.
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