N-alkylated derivatives of thienamycin sulfoxide and sulfone

Drug – bio-affecting and body treating compositions – Antigen – epitope – or other immunospecific immunoeffector – Fungus – except allergen – or component thereof or substance...

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546200, 546272, 2603068R, 2603068D, 2603068A, 260307H, 260307G, 260308D, 260308R, 26032625, 4242485, 424250, 424263, 424267, 424269, 424270, 424272, 424273R, 542416, 544144, 544238, 544282, 544351, 548336, C07D48704, A16K 3140

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041501454

ABSTRACT:
Disclosed are N-alkylated derivatives of thienamycin sulfoxide (I, n=1) and sulfone (I, n=2): ##STR1## wherein n=1 or 2; and R.sup.5, R.sup.6, and R.sup.7 are, inter alia, hydrogen or alkyl. Such compounds the their pharmaceutically acceptable O- and carboxyl- derivatives are useful as antibiotics. Also disclosed are processes for the preparation of such derivatives, pharmaceutical compositions comprising such derivatives and methods of treatment comprising administering such derivatives and compositions when an antibiotic effect is indicated.

REFERENCES:
patent: 3862181 (1975-01-01), Davis et al.
patent: 3950357 (1976-04-01), Rahan et al.
patent: 4000129 (1976-12-01), Verwey et al.
patent: 4000161 (1976-12-01), Geogelman et al.
patent: 4022773 (1977-05-01), Ishimaru
Brown et al.; J. C. S. Chem. Comm. (1977) p. 523.
Maeda et al.; J. Antibiotics vol. 30 (1977) p. 770.
Fieser et al.; Advanced Organic Chemistry p. 313 (1961).

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