Multi-fluid polishing process

Abrading – Abrading process – With tool treating or forming

Reexamination Certificate

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C451S443000

Reexamination Certificate

active

06572453

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to the field of semiconductor processing, and more particularly to a method and apparatus for polishing and/or planarizing semiconductor wafers and the thin films formed thereon.
BACKGROUND OF THE INVENTION
Semiconductor devices are formed on silicon substrates and are typically multi-layered, having numerous metalization layers separated by numerous insulating oxides and interconnected with vias or contact holes. For instance, an interconnect for a typical multi-layer device is formed by depositing and patterning a first metal layer over the device, depositing an intermediate oxide over the patterned first metal layer, photolithographically defining a contact hole in the oxide, and depositing a second metal layer over the oxide that fills the contact hole and contacts the patterned first metal layer.
Often undesirable steps or undulations must be removed from the silicon substrate or from one of the metal or oxide layers before another layer can be formed thereon. To remove steps or undulations, the silicon oxide or metal is preferably planarized, removing any steps or undulations formed therein, prior to deposition of a layer thereon. Planarization is typically performed mechanically by forcing the semiconductor wafer face down against a polishing pad which is saturated with a polishing fluid (e.g., a slurry or polishing chemical) and by moving the polishing pad relative to the wafer. The relative movement between the polishing pad and the wafer mechanically removes layers of material and is continued until the steps or undulations are removed. This process is generally referred to as chemical mechanical polishing (CMP).
To facilitate material removal during the CMP process the polishing pad may be provided with grooves that channel polishing fluid to the polishing pad/wafer interface, and that provide a path for wafer material to be removed from the polished wafer surface, and/or the pad may be made porous to hold the slurry chemical and polishing by-product.
During polishing, however, the downward force of the wafer against the polishing pad compacts polishing fluid particles and polishing by products within these grooves and porous structures, reducing the supply of fresh polishing fluid or polishing chemical to the polishing pad/wafer interface, reducing friction between the wafer and the pad, reducing the removal rate of wafer material, and the overall polishing efficiency, uniformity and throughput of the CMP process, as well as giving rise to defects in the form of wafer scratches, as described below, and increasing dishing of the wafer surface. Additionally, the downward force of the wafer against the polishing pad causes the semi-porous surface of the polishing pad to pack down, causing polishing rates to become low and unpredictable, and necessitating frequent polishing pad replacement.
To extend the useful life of a polishing pad, a pad conditioner that roughens or “conditions” the polishing pad surface is employed in-situ, while the polishing pad polishes a wafer and while a polishing chemical/slurry is supplied to the pad surface; or ex-situ, after wafer polishing is complete, and while deionized water is supplied to the pad surface. A typical pad conditioner comprises a diamond surface that roughens the polishing pad surface by scribing additional “microgrooves” in the polishing pad surface. Roughening of the polishing pad surface ensures adequate abrasion (e.g., due to polishing fluid saturation of the roughened surface) at the polishing pad/wafer interface. In certain applications however, unstable polishing rates none-the-less persist. Accordingly, an improved polisher method and apparatus is needed.
SUMMARY OF THE INVENTION
The present inventors have discovered that polishing of wafers having certain material layers (e.g., copper layers) deposited thereon results in the build up of materials on the polishing pad. Such build up is not removable via conventional conditioning methods. Accordingly the present invention provides a method and apparatus that avoids the build up of polishing by products from the polishing pad without the reduction in throughput associated with conventional ex-situ conditioning. Conventional ex-sit conditioning tends to reduce system throughput as additional time is required for moving the wafer into and out of contact with the polishing pad. Specifically, a polishing method is provided which simultaneously supplies both a polishing fluid and a conditioning fluid to a polishing pad, while a substrate is in moving contact with the polishing pad.
Other features and advantages of the present invention will become more fully apparent from the following detailed description of the preferred embodiments, the appended claims and the accompanying drawings.


REFERENCES:
patent: 3889753 (1975-06-01), Richardson
patent: 4090563 (1978-05-01), Lybarger et al.
patent: 4541945 (1985-09-01), Anderson et al.
patent: 4954142 (1990-09-01), Carr et al.
patent: 4959113 (1990-09-01), Roberts
patent: 5084071 (1992-01-01), Nenandic et al.
patent: 5216843 (1993-06-01), Breivogel et al.
patent: 5225034 (1993-07-01), Yu et al.
patent: 5340370 (1994-08-01), Cadien et al.
patent: 5478436 (1995-12-01), Winebarger et al.
patent: 5509970 (1996-04-01), Shiramizu
patent: 5527423 (1996-06-01), Neville et al.
patent: 5645682 (1997-07-01), Skrovan
patent: 5662769 (1997-09-01), Schonauer et al.
patent: 5664990 (1997-09-01), Adams et al.
patent: 5755614 (1998-05-01), Adams et al.
patent: 5830280 (1998-11-01), Sato et al.
patent: 5840629 (1998-11-01), Carpio
patent: 5876508 (1999-03-01), Wu et al.
patent: 5879226 (1999-03-01), Robinson
patent: 5916010 (1999-06-01), Varian et al.
patent: 5934980 (1999-08-01), Koos et al.
patent: 5957757 (1999-09-01), Berman
patent: 5961373 (1999-10-01), Lai et al.
patent: 5975994 (1999-11-01), Sandhu et al.
patent: 5981454 (1999-11-01), Small
patent: 6022266 (2000-02-01), Bullard et al.
patent: 6030487 (2000-02-01), Fisher, Jr. et al.
patent: 6033993 (2000-03-01), Love, Jr. et al.
patent: 6046110 (2000-04-01), Hirabayashi et al.
patent: 6060396 (2000-05-01), Fukami et al.
patent: 6083840 (2000-07-01), Marvic et al.
patent: 6100197 (2000-08-01), Hasegawa
patent: 6162301 (2000-12-01), Zhang et al.
patent: 6165956 (2000-12-01), Zhang et al.
patent: 6179693 (2001-01-01), Beardsley et al.
patent: 6234877 (2001-05-01), Koos et al.
patent: 6263605 (2001-07-01), Vanell
patent: 6352595 (2002-03-01), Svirchevski et al.
patent: 6376345 (2002-04-01), Ohashi et al.
patent: 2154234 (1973-05-01), None
patent: 3424329 (1986-01-01), None
patent: 39 39 661 (1991-06-01), None
patent: 0 401 147 (1990-12-01), None
patent: 0 496 605 (1992-07-01), None
patent: 0 860 860 (1998-08-01), None
patent: 2 722 511 (1995-07-01), None
patent: 87-160406 (1988-04-01), None
patent: WO 99/46353 (1999-09-01), None
Bennett et al., “Multiple-Step Conditioning Process”, Oct. 11, 2000, US 2001/0029155 A1, entire document.*
Pak, “Impact of EDTA on junction and photolith qualities”, Extended Abstracts, Oct. 1980, vol. 80, No. 2, pp. 1241-1243.
Kern, “Radiochemical study of semiconductor surface contamination”, RCA Review, Jun. 1970, vol. 31, pp. 207-264, see p. 249.
Kaufman et al., “Chemical-mechanical polishing for fabricating patterned W metal features as chip interconnects”, Journal of the Electrochemical Society, vol. 138, No. 11, Nov. 1991, pp. 3460-3464.
Greer et al., “Process for removing wafer surface contaminants”, IBM Technical Disclosure Bulletin, vol. 15, No. 8, Jan. 1973, p. 2358.
Patent Abstracts of Japan, vol. 16, No. 29 (C-904), Jan. 24, 1992 & JP 3242352, Oct. 29, 1991.
Hymes et al., “The Challenges of the Copper CMP Clean”, Semiconductor International, pp. 117-122 (1998).
Zhao et al., “Copper CMP Cleaning Using Brush Scrubbing”, 1998 CMP-MIC Conference, pp. 359-366 (1998).
Brusic et al., “Copper Corrosion With and Without Inhibitors”, J. Electrochem, Soc., vol. 138, No. 8, Aug. 1991.

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