Modified supported metathesis catalysts

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By alkyl transfer – e.g. – disproportionation – etc.

Reexamination Certificate

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Details

C585S647000, C585S353000, C585S354000

Reexamination Certificate

active

07145050

ABSTRACT:
The invention relates to modified supported catalysts based on Re2O7/γ-Al2O3for use in the preparation of cycloalkadienes in a metathesis reaction, a process for preparing cycloalkadienes in the presence of these supported catalysts and the use of the resulting cycloalkadienes for the preparation of fragrances.

REFERENCES:
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patent: 5898092 (1999-04-01), Commereuc
patent: 2003/0069460 (2003-04-01), Wohrle et al.
patent: 2003/0230598 (2003-12-01), Kendall et al.
patent: 197 27 256 (1999-01-01), None
patent: 1 216 587 (1968-09-01), None
J.C. Mol, Olefin Metathesis Over Supported Rhenium Catalysts, 1999, vol. 51, pp. 289-299, paragraphs 3.1.1, 3.1.3 and 03.2, no month.
J. Hietala et al, The Surface Acidity of Pure and Modified Aluminas in Re/A1203 Metathesis Catalysts as Studied by 1H MAS NMR Spectroscopy and Its Importance in the Ethenolysis od 1,5-Cyclooctadiene, 1984, vol. 150, pp. 46-55, examples 14-18, 21 and 22, table 1, pp. 26 and 47, no month.
Kawai et al, Metathesis of N-Alkenes Over a CsN03-Re207-A1203 Catalyst, 1988, vol. 46, pp. 157-172, p. 158, no month.
Xiaoding X et al., Re207/A1203.B203 Metathesis Catalyst, 1986, vol. 82, pp. 1945-1953, no month.

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